| Chapter 1: The World-Centric Comedy about Nation Personifications is our Shocking New Serialisation! (2014/09/22) | Germany, Italy
France, Liechtenstein, Spain |
| Chapter 2: The Anticipated New Serialisation! Second Chapter... Suddenly Rome!? (2014/09/26) | Agrippina, Nero
Poppaea |
| Chapter 3: After the Rain, There's Hetalia! (2014/09/29) | Germany, Italy |
| Chapter 4: Still Touring (2014/10/03) | Germany, Italy |
| Chapter 5: Emperor Nero... The Forgotten Days... (2014/10/06) | Agrippina, Nero
Commodus |
| Chapter 6: Emperor Nero's Half-wit Days! (2014/10/10) | Nero
Anicetus |
| Chapter 7: Germany Takes a Break! (2014/10/13) | Germany, Italy |
| Chapter 8: News Flash! Italy's Gotten Fat!? (2014/10/17) | Germany, Italy
America |
| Chapter 9: Who is This Man Calling Emperor Nero a Fucking Brat!? (2014/10/20) | Anicetus, Burrus, Nero, Seneca
Agrippina |
| Chapter 10 (2014/10/24) | Anicetus, Burrus, Nero, Seneca
Didius Julianus, Diocletian, Heliogabalus, Valerian |
| Chapter 11: Anime is the Universal Language of the Whole World...! (2014/10/27) | Germany, Italy |
| Chapter 12: The Secret Story of His Birth! (2014/10/31) | Austria, Germany, Prussia
Italy |
| Chapter 13: Roman Emperor Picture Book ~Augustus (27BC - 14AD)~ (2014/11/03) | Agrippa, Augustus,
Caesar, Cleopatra, Mark Antony |
| Chapter 14: Roman Emperor Picture Book ~Tiberius (14BC - 37AD)~ ~Caligula (37 - 41AD)~ (2014/11/07) | Caligula, Tiberius
Nero, Thrax |
| Chapter 15: This is Japan! (2014/11/10) | Germany, Italy, Japan
Romano |
| Chapter 16: A Melody That Transcends History and Reaches You... (2014/11/14) | Germany, Italy, Japan
America, Romano |
| Chapter 17: Roman Emperor Picture Book ~Claudius (41AD - 54AD)~ (2014/11/17) | Claudius |
| Chapter 18: Roman Emperor Picture Book ~Extra Edition: Antony~ (2014/11/21) | Caesar, Cleopatra, Mark Antony
Augustus |
| Chapter 19: Catches on Fast (2014/11/24) | Germany, Italy, Romano |
| Chapter 20: Italy-kun has an Older Brother (2014/11/28) | Germany, Italy, Romano
Spain |
| Chapter 21: The Mood is Positive (2014/12/01) | Ancient Rome, Augustus, Caligula, Claudius, Nero, Tiberius
Ancient Egypt, Ancient Greece, Germania, Persia, Pontus |
| Chapter 22: Light Discussion and a Surprising Proposal (2014/12/05) | Anicetus, Burrus, Nero, Seneca |
| Chapter 23: This is America! (2014/12/08) | America, Italy, Japan
England, France, Germany |
| Chapter 24: Hi! What's Up! (2014/12/12) | America, Germany, Italy, Japan |